The petrology of the peralkaline felsic lavas from the Ngaoundéré region was re-examined,
together with new chronological data obtained on them, in order to determine their petrogenesis
and investigate their peralkaline features. The results showed that all lavas have a microlitic
porphyritic texture. They are composed of more than 70% phenocrysts and microlites of alkali
feldspar, with diopside, hedembergite, augite, aegirine-augite for trachytes, and nosean,
nepheline, kaersutite, titanite, apatite and oxides¸ set in a matrix of the same minerals, in
phonolite. All lavas, Miocene in age, are the result of the fractional crystallization processes
undergone by the surrounding basaltic lavas. The titanite crystallization phase is responsible for
the concave downward appearance of the REE pattern of peralkaline phonolite, as well as the
slight depletion of Nb and Ta. AFC modeling using Pan-African basement rock as contaminant
was also intended. The genesis of peralkaline trachytes from less-evolved lavas requires a
Ma/Mc ratio of 0.1, and a fractionation process (F ≈ 0.9) involving only feldspar so as to comply
with the (87Sr/86Sr) 9Ma values of ≈ 0.710. Additionally, hydrothermal fluid effects are
suspected. The peralkalinity of the lavas is the result of a pronounced fractionation of the Al2O3
component by aluminous-enriched phases, in combination with alkali- and volatile-enriched
metasomatized fluids, which have acted through the network of Pan-African cracks.
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