Article
The Distribution of Zr, Hf and Y in the soils of Iaşi Municipality: Case Study
Laviniu Apostoae - “Alexandru Ioan Cuza” University of Iaşi, Department of Geology
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Abstract:
Zr, Hf and Y contents were determined via 54 samples collected from the topsoils of the
Botanical Garden in Iaşi. Statistical parameters suggest the presence of a relatively homogeneous
population whose mean values (Zr = 265.733 mg·kg-1, Hf = 7.287 mg·kg-1, Y= 27.524
mg·kg-1) fall within the Zr, Hf and Y content variation range, determined in other urban soils in
the world, but they are higher than the mean values calculated by various authors for the upper
continental crust. Although positive, the correlation coefficients have significant values only for
Zr–Hf (0.539) and Zr–Y (0.325). The values of the geochemical background determined via the
upper 95% confidence limit of the 95th percentile, namely 267.174 mg·kg-1 (Zr), 7.297 mg·kg-1
(Hf) and 34.079 mg·kg-1 (Y), are higher than the mean calculated values for the upper
continental crust. The distribution of values of the Zr·Hf-1, Zr·Y-1 and Hf·Y-1 ratios reflects, first
of all, the geochemical characteristics of the predominant lithology, namely loesses in the
northern area and clays in the southern area, potential anthropic inputs being limited to fertilizers
specific to the flora in the Botanical Garden.
Keywords:
soil, zirconium, hafnium, yttrium, geochemical background, Iaşi, Romania
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