Article
Geochemical distribution of selected trace elements in the soil-plant system from Mănăila mining area, Romania
Simona Petronela Iftode - “Al. I. Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology, 20A Carol I Blv., 700505 Iaşi, Romania, Department of Geology Ramona Huzum - “Al. I. Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology, 20A Carol I Blv., 700505 Iaşi, Romania, Department of Geology Doina Smaranda Sîrbu-Rădășanu - “Al. I. Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology, 20A Carol I Blv., 700505 Iaşi, Romania, Department of Geology Nicolae Buzgar - “Al. I. Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology, 20A Carol I Blv., 700505 Iaşi, Romania, Department of Geology Ovidiu Gabriel Iancu - “Al. I. Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology, 20A Carol I Blv., 700505 Iaşi, Romania, Department of Geology Andrei Buzatu - “Al. I. Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology, 20A Carol I Blv., 700505 Iaşi, Romania, Department of Geology
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Abstract:
This study presents the geochemical distribution of several trace elements (TE) (Ni, Cu, Zn, As,
Pb) in a soil-plant system, taking into account the lingonberry, a shrub most widely spread
around the Mănăila mining region in Suceava County. A number of 34 samples (soil and the
plant above), collected arround the open pit, was prepared for the analysis of soils – using EDXRF
method and separated plant organs (roots, leaves, fruits) – using ICP-MS, after HNO3
microwave digestion.
Compared with Romanian legislative values, the soil from the surroundings of the Mănăila open
pit present contents for Ni and Zn within the normal values; Cu ranges between normal and alert
threshold, while As and Pb exceed the alert threshold. The geo-accumulation index (Igeo) average
values point out to a moderate contamination with As, Pb and Cu and support a higher potential
toxicity risk for these elements. Based on the bioconcentration factor (BCF), the lingonberry
behaves as an indicator for Cu and Zn and as an excluder for Ni, As and Pb. The transfer factor
(TF) values show an accumulation at the aboveground plant parts for Ni and Cu.
Keywords:
TE, TF, BCF, soil-plant system, mining area, Vaccinium vitis idaea
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