Article
Geochemical and hydrodynamic control of trace element transport in a reservoir: impact of interflow layer
Nathalie Gassama - Université François-Rabelais de Tours, GéHCO Géohydrosystèmes Continentaux, Constantin Cocîrță - Université François-Rabelais de Tours, GéHCO Géohydrosystèmes Continentaux, Haino Uwe Kasper - Universität zu Köln, Institut für Geologie und Mineralogie
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Abstract:
Concentration of trace elements both in the water column (dissolved phase and acid-soluble
suspended particles) and in sediments (bulk and acid-soluble particles) was followed for one
year in a water reservoir (the Bicaz reservoir) used for electricity production. This study
investigated the impact of river inflows, outflows and the position of the outflow for the cycling
and the transport of these elements along this water reservoir. Time series results reveal that
river inflow supplies mainly reducing waters. In the water column, the stable Al/Fe ratio (from
0.8 to 1.5) recorded in acid-soluble suspended particles suggests the formation of similar
amorphous phases during the year, phases that could be stabilized by organic ligands. In
sediments, these amorphous phases are no more recorded. In the water column, some trace
elements are strongly associated with Al-Fe amorphous phases (Rb, Cs, Co, Cu, Zn, Pb, Th);
others are independent (Sr, Sn, As, Sb, U). In sediments, Co, Y, Zn, Ga, Cr, Ni, V, Rb, and Ba
are associated with phases containing Fe, Al, K, Mg, P and Ti. The reservoir acts as a moderate
sink for Fe, V, Cr, Co, Cu; it acts alternately as a sink and a source for Zn. Among the elements
studied, only Mn and Ni are significantly stored. Rb shows particular affinity for Fe oxide which
is not recorded in literature. Our results show the importance of the outflow depth on the
transport of trace elements within a reservoir.
Keywords:
reservoir, Al-Fe particles, trace elements, redox condition, interflow layer, water
column, sediments
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